Cracking Of Propane Equation
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Steam cracking is a petrochemical process in which saturated hydrocarbons are broken down into smaller, often unsaturated, hydrocarbons. It is the principal industrial method for producing the lighter alkenes (or commonly olefins), including ethene (or ethylene) and propene (or propylene). Steam cracker units are facilities in which a feedstock such as naphtha, liquefied petroleum gas (LPG), ethane, propane or butane is thermally cracked through the use of steam in steam cracking furnaces to produce lighter hydrocarbons. The propane dehydrogenation process may be accomplished through different commercial technologies. The main differences between each of them concerns the catalyst employed, design of the reactor and strategies to achieve higher conversion rates.[1]
In steam cracking, a gaseous or liquid hydrocarbon feed like naphtha, LPG, or ethane is diluted with steam and briefly heated in a furnace in the absence of oxygen.[3] Typically, the reaction temperature is very high, at around 850 °C. The reaction occurs rapidly: the residence time is on the order of milliseconds. Flow rates approach the speed of sound. After the cracking temperature has been reached, the gas is quickly quenched to stop the reaction in a transfer line heat exchanger or inside a quenching header using quench oil.[2]
The products produced in the reaction depend on the composition of the feed, the hydrocarbon-to-steam ratio, and on the cracking temperature and furnace residence time. Light hydrocarbon feeds such as ethane, LPGs, or light naphtha give mainly lighter alkenes, including ethylene, propylene, and butadiene. Heavier hydrocarbon (full range and heavy naphthas as well as other refinery products) feeds give some of these same products, but also those rich in aromatic hydrocarbons and hydrocarbons suitable for inclusion in gasoline or fuel oil.[citation needed]
A higher cracking temperature (also referred to as severity) favors the production of ethene and benzene, whereas lower severity produces higher amounts of propene, C4-hydrocarbons and liquid products. The process also results in the slow deposition of coke, a form of carbon, on the reactor walls. This degrades the efficiency of the reactor, so reaction conditions are designed to minimize this. Nonetheless, a steam cracking furnace can usually only run for a few months at a time between de-cokings. Decokes require the furnace to be isolated from the process and then a flow of steam or a steam/air mixture is passed through the furnace coils. This converts the hard solid carbon layer to carbon monoxide and carbon dioxide. Once this reaction is complete, the furnace can be returned to service.[citation needed]
Even though the thorough energy integration within a steam cracking plant, this process produces an unsurmountable amount of carbon dioxide. Per tonne of ethylene, 1 - 1.6 tonne of carbon dioxide (depending on the feedstock) is being produced.[4] Resulting in a staggering amount of more than 300 million tonnes of carbon dioxide that is annually emitted into the atmosphere of which 70-90% is directly attributed to the combustion of fossil fuel. In the last few decades, several advances in steam cracking technology have been implemented to increase its energy efficiency. These changes include oxy-fuel combustion, new burner technology, and 3D reactor geometries.[4] However, as is common within mature technologies these changes only led to marginal gains in energy efficiency. To drastically curb the greenhouse gas emission of steam cracking, electrification does offer a solution as renewable electricity can be directly transformed into heat by, for example, resistive and inductive heating.[4] As a result, several petrochemical companies joined forces resulting in the development of several joint agreements in which they combine R&D efforts to investigate how naphtha or gas steam crackers could be operated using renewable electricity instead of fossil fuel combustion.[5][6]
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Ethylene is a critical building block for the petrochemical industry, and is among the most produced organic compounds. It is usually produced in steam-cracking units from a range of petroleum-based feedstocks, such as naphtha, and is used in the manufacture of several major derivatives.
The process shown in Figure 1 is a steam-cracking process for ethylene production from an ethane-propane mixture. The process can be divided into three main parts: cracking and quenching; compression and drying; and separation.
Cracking and quenching. Initially, an ethane-propane mixture is fed to furnaces in which, under high-severity conditions, it is cracked, forming ethylene, propylene and other byproducts. The furnace outlet stream is subsequently fed to a water-based quench, to prevent further reactions and formation of undesirable byproducts.
The top of the deethanizer, composed primarily of ethylene and ethane, is fed to an acetylene converter and then fractionated in the C2-splitter. In this column, lights are removed from the overheads and recycled to the compression system, while polymer-grade (PG) ethylene is drawn from the column as a side stream. Ethane, from C2-splitter bottoms, is recycled to the cracking furnaces.
The deethanizer bottom stream is fed to a depropanizer, which distills C3 components in the overheads. This overhead stream is catalytically hydrotreated for methyl acetylene and propadiene removal, and then fed to the C3-splitter. In this column, lights are removed from the overheads and recycled to the compressors, while polymer-grade (PG) propylene is drawn from the column as a side stream. Propane from C3-splitter bottoms is recycled to the cracking furnaces. A C4+ stream is obtained from the depropanizer bottoms.
The source of the large hydrocarbon molecules is often the naphtha fraction or the gas oil fraction from the fractional distillation of crude oil (petroleum). These fractions are obtained from the distillation process as liquids, but are re-vaporised before cracking.
Modern cracking uses zeolites as the catalyst. These are complex aluminosilicates, and are large lattices of aluminium, silicon and oxygen atoms carrying a negative charge. They are, of course, associated with positive ions such as sodium ions. You may have come across a zeolite if you know about ion exchange resins used in water softeners.
The zeolites used in catalytic cracking are chosen to give high percentages of hydrocarbons with between 5 and 10 carbon atoms - particularly useful for petrol (gasoline). It also produces high proportions of branched alkanes and aromatic hydrocarbons like benzene.
Note: If you are interested in other examples of catalysis in the petrochemical industry, you should follow this link. It will lead you to information on reforming and isomerisation (as well as a repeat of what you have just read about catalytic cracking).
In thermal cracking, high temperatures (typically in the range of 450°C to 750°C) and pressures (up to about 70 atmospheres) are used to break the large hydrocarbons into smaller ones. Thermal cracking gives mixtures of products containing high proportions of hydrocarbons with double bonds - alkenes.
Warning! This is a gross oversimplification, and is written to satisfy the needs of one of the UK A level Exam Boards (AQA). In fact, there are several versions of thermal cracking designed to produce different mixtures of products. These use completely different sets of conditions.
If you need to know about thermal cracking in detail, a Google search on thermal cracking will throw up lots of useful leads. Be careful to go to industry (or similarly reliable) sources.
Thermal cracking doesn't go via ionic intermediates like catalytic cracking. Instead, carbon-carbon bonds are broken so that each carbon atom ends up with a single electron. In other words, free radicals are formed.
Note: If you are interested, there is a lot of really useful information on cracking on this page from the Essential Chemical Industry. You will be reading that out of interest, not because you need to know it all!
Abstract:Light olefins are the main building blocks used in the petrochemical and chemical industries for the production of different components such as polymers, synthetic fibers, rubbers, and plastic materials. Currently, steam cracking of hydrocarbons is the main technology for the production of light olefins. In steam cracking, the pyrolysis of feedstocks occurs in the cracking furnace, where hydrocarbon feed and steam are first mixed and preheated in the convection section and then enter the furnace radiation section to crack to the desired products. This paper summarizes olefin production via the steam cracking process; and the reaction mechanism and cracking furnace are also discussed. The effect of different operating parameters, including temperature, residence time, feedstock composition, and the steam-to-hydrocarbon ratio, are also reviewed.Keywords: olefin production; steam cracking; cracking furnace; ethylene; propylene; butenes; reaction parameters
Before hydraulic fracturing revolutionized the way we produce natural gas and NGLs in the U.S., most steam cracking furnaces used naphtha as the primary feedstock. Because oil prices were much lower overseas, many U.S.-based steam cracking plants were forced to close, as they were simply not competitive on a global scale. This all changed when hydraulic fracturing shale formations provided inexpensive and plentiful supplies of natural gas and NGLs, which are rich in ethane. American petrochemical manufacturers are now very competitive globally and are expanding ethane cracking capacity.
Steam cracking furnaces for ethane are similar to those using naphtha. In fact, many U.S. steam crackers are designed to run either feedstock. However, the actual cracking reaction must be carefully tailored depending on the composition of the feedstock as well as the desired end product. The temperature in the cracking furnace, the residence time of the feedstock, and the quenching process used all affect the quality of the produced hydrocarbon stream. Once the feedstock has been cracked, the product stream must be purified and separated, using various processes depending on the feedstock. These furnaces must occasionally be de-coked, which requires injecting flammable gas into the furnace in order to burn residue (coke) off of the tubes carrying the hydrocarbon feedstock. 2b1af7f3a8
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